Hey, I've had this as my desktop background for almost a decade now! Easily my favorite picture of anything "space".
As for your question, it looks like Pluto has an atmosphere in the picture because, well, it does. Although it's very thin, Pluto's atmosphere is primarily nitrogen, so if you stood on the surface during daytime the sky would appear a very familiar blue color.
Pluto's atmosphere has been studied since the 1980s, using spectroscopy and stellar occultation (watching starlight flicker as Pluto passed in front of it). It wasn't a surprise when New Horizons observed it.
Always "Pluto, Pluto, Pluto". Why does no one ever remember Ceres, Eris, Haumea, and Makemake? They're each as much of a planet as Pluto is. Dwarf planets, but planets nonetheless.
I use this photo as my computer background, it looks so good with a multiple monitor setup or extended display. Sadly I have only my laptop, I do miss having an extra monitor.